VIBRATIONAL SPECTRA AND FORCE CONSTANTS FOR ISOTOPIC SPECIES OF NITROSYL CHLORIDE

被引：103

作者：

JONES, LH

RYAN, RR

ASPREY, LB

机构：

[1] Los Alamos Scientific Laboratory, University of California, Los Alamos, NM

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 49卷 / 02期

关键词：

D O I：

10.1063/1.1670112

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From infrared absorption studies in the gaseous phase, fundamental harmonic vibrational frequencies have been determined for 15O 14N35Cl, 16O1535Cl, 18O14N35Cl, and 18O 15N35Cl. With the aid of centrifugaldistortion data from the literature, a unique general quadratic valence-force-constant solution was obtained. The resulting values are: FNO=15.26 mdyn Å-1, FNCl=1.27 mdyn Å-1, F α=1.32 mdyn Å-1·rad-2, FNO,NCl= 1.53 mdyn Å-1, FNO,α=0.1 mdyn rad-1, FNCl,α=0.12 mdyn rad-1.

引用

页码：581 / &

共 12 条

[1] THE VIBRATIONAL SPECTRA AND STRUCTURE OF INORGANIC MOLECULES .3. THE INFRA-RED SPECTRA OF NITROSYL CHLORIDE AND NITROSYL BROMIDE FROM 2.0-MU TO 25-MU [J].