SYNTHESIS OF 5,7-DIHYDRO-6H-NAPHTHO-[1',2'/5,6]PYRANO[3,2-C]QUINOLIN-6-ONES

被引:0
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作者
GUPTA, MCLN [1 ]
DARBARWAR, M [1 ]
机构
[1] OSMANIA UNIV,DEPT CHEM,HYDERABAD 500007,ANDHRA PRADESH,INDIA
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D O I
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Acid catalysed condensation of 3-formyl-4-hydroxyquinolin-2(1H)-ones (1) with 2-naphthol (2) furnishes two different 7-substituted 5,7-dihydro-6H-naphtho[1',2':5,6]pyrano[3,2-c]quinolin-6-ones 3 and 4. A mechanistic pathway for the formation of 3 and 4 has been described. The structure of the unexpected product 4 has been supported by an independent synthesis starting from 4-hydroxyuinolin-2(1H)-ones (11) and 2-hydroxy-1-naphthaldehyde (12).
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页码:1080 / 1082
页数:3
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