THE CHEMISTRY OF RU(OEP)(CH3) - A CH3 TO CO TRANSFORMATION

被引:23
|
作者
SEYLER, JW [1 ]
FANWICK, PE [1 ]
LEIDNER, CR [1 ]
机构
[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907
关键词
D O I
10.1021/ic00044a008
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first example of a CH3 to CO transformation involving a metal complex has been uncovered as part of the study of the reaction chemistry of Ru(OEP)(CH3). Isotope labeling and IR spectroscopy verify CH3 as the source of CO. [GRAPHICS]
引用
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页码:3699 / 3700
页数:2
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