CHARACTERIZATION OF HYDRODYNAMIC LIFT FORCES BY FIELD-FLOW FRACTIONATION - INERTIAL AND NEAR-WALL LIFT FORCES

被引:105
|
作者
WILLIAMS, PS
LEE, SH
GIDDINGS, JC
机构
[1] Field-Flow Fractionation Research Center, Department of Chemistry, University of Utah, Salt Lake City
[2] 201 Corporate Research, St. Paul, MN 55144
基金
美国国家科学基金会;
关键词
FIELD-FLOW FRACTIONATION; HYDRODYNAMIC LIFT FORCE; INERTIAL LIFT FORCE;
D O I
10.1080/00986449408936272
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Sedimentation/steric FFF has been used to measure hydrodynamic lift forces exerted on 2-30 mu m latex microspheres driven by flow through a 95 cm long ribbonlike FFF channel of similar to 127 mu m thickness. Following a previous study, lift forces are examined as a function of shear rate, distance from the waif, and sphere size. Here, in contrast to the earlier study, measured lift forces are extended downward into a range corresponding to theoretical values of the inertial lift force. After corrections are made for secondary relaxation, itis found, as before, that a near-wall lift force proportional to 1/delta (where delta is the particle-wall distance) dominates lift effects at small delta s. As delta increases and this force decays, the measured lift force assumes a value in good agreement with the inertial lift force predicted by the theory of Cox and Brenner as extended by subsequent workers. Over a broad range of conditions explored in almost 300 measurements, the results are consistent with a total lift force that equals the sum of near-wall and inertial contributions. Possible sources of error in the analysis are examined and various explanations for the near-wall lift force are discussed.
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页码:143 / 166
页数:24
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