A HIGHLY STRAINED HETEROCYCLOSILOXANE - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF PENTAPHENYLBORACYCLOTRISILOXANE BSI2O3PH5

被引：23

作者：

FOUCHER, DA ^{[1
]}

LOUGH, AJ ^{[1
]}

MANNERS, I ^{[1
]}

机构：

[1] UNIV TORONTO,DEPT CHEM,80 ST GEORGE ST,TORONTO M5S 1A1,ONTARIO,CANADA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)83249-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first X-ray structure determination of a neutral, uncomplexed molecular cyclotrisiloxane in which a skeletal silicon atom has been replaced by an atom of a heteroelement shows that BSi2O3Ph5 possesses a highly strained six-membered ring with considerable bond angle distortion.

引用

页码：C1 / C4

页数：4

共 17 条

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