A HIGHLY STRAINED HETEROCYCLOSILOXANE - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF PENTAPHENYLBORACYCLOTRISILOXANE BSI2O3PH5

被引：23

作者：

FOUCHER, DA ^{[1
]}

LOUGH, AJ ^{[1
]}

MANNERS, I ^{[1
]}

机构：

[1] UNIV TORONTO,DEPT CHEM,80 ST GEORGE ST,TORONTO M5S 1A1,ONTARIO,CANADA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)83249-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first X-ray structure determination of a neutral, uncomplexed molecular cyclotrisiloxane in which a skeletal silicon atom has been replaced by an atom of a heteroelement shows that BSi2O3Ph5 possesses a highly strained six-membered ring with considerable bond angle distortion.

引用

页码：C1 / C4

页数：4

共 17 条

[1] REACTIONS OF FERROCENYLPHOSPHAZENES AND RUTHENOCENYLPHOSPHAZENES WITH LITHIOMETALLOCENES AND THE X-RAY STRUCTURES OF N3P3F4(ETA-C5H4)2FE, [N3P3F3((ETA-C5H4)2FE)((ETA-C5H4)FE(ETA-C5H5))], 1,5-N4P4F6(ETA-C5H4)2FE, AND 1,5,3,7-N4P4F4[(ETA-C5H4)2RU]2 [J].

ALLCOCK, HR ;

LAVIN, KD ;

RIDING, GH ;

WHITTLE, RR ;

PARVEZ, M .

ORGANOMETALLICS, 1986, 5 (08) :1626-1635

[2] RING-OPENING POLYMERIZATION OF METALLOCENE CYCLOPHOSPHAZENE DERIVATIVES [J].

ALLCOCK, HR ;

LAVIN, KD ;

RIDING, GH .

MACROMOLECULES, 1985, 18 (06) :1340-1345

[3]

BARROW MJ, 1979, ACTA CRYSTALLOGR B, V35, P2093, DOI 10.1107/S0567740879008529

[4]

BOKII NG, 1972, ZH STRUKT KHIM, V13, P291

[5]

COLEY SM, UNPUB

[6]

COLEY SM, 1991, MACROMOLECULES, V24, P2024

[7]

DODGE JA, UNPUB ORGANOMETALLIC

[8]

DODGE JK, UNPUB

[9] PREPARATION AND CRYSTAL-STRUCTURE OF THE TITANASPIRO[7.7]HEPTASILOXANE CIS-BIS(HEXAPHENYLTRISILOXANEDIOLATO)DIPYRIDINE-TITANIUM BIS(TOLUENE) SOLVATE [J].

HOSSAIN, MA ;

HURSTHOUSE, MB ;

MAZID, MA ;

SULLIVAN, AC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (19) :1305-1306

[10] OCTAPHENYLCYCLOTETRASILOXANE - MONOCLINIC FORM [J].

HOSSAIN, MA ;

HURSTHOUSE, MB ;

MALIK, KMA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (FEB) :522-524

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