FACILE FORMATION OF A BRIDGING CYCLOOCTATRIENEYNE LIGAND - SYNTHESIS AND MOLECULAR-STRUCTURE OF [(ETA-C8H6(SIME(3))(2))ZR(CH(SIME(3))(2))(MU-ETA(8)ETA(2)-C8H4(SIME(3))(2))ZR(CH(SIIME(3))(2))]

被引：8

作者：

CLOKE, FGN

HITCHCOCK, PB

JOSEPH, SCP

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 10期

关键词：

D O I：

10.1039/c39940001207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between the bridging chloride dimer [{Zr(eta-COT'')Cl-2}(2)] [COT'' = 1,4-bis(trimethylsilyl)cyclooctatetraene] and [LiCH(SiMe(3))(2)] affords the title complex; whose X-ray structure reveals a bridging cyclooctatrieneyne ligand resulting from double hydrogen abstraction from a COT ring.

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页码：1207 / 1208

页数：2

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