SYNTHESIS, CHARACTERIZATION, AND CURING OF HYPERBRANCHED ALLYL ETHER MALEATE FUNCTIONAL ESTER RESINS

被引：176

作者：

JOHANSSON, M ^{[1
]}

MALMSTROM, E ^{[1
]}

HULT, A ^{[1
]}

机构：

[1] ROYAL INST TECHNOL,DEPT POLYMER TECHNOL,S-10044 STOCKHOLM 70,SWEDEN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1993年 / 31卷 / 03期

关键词：

ALLYL ETHER; HYPERBRANCHED; RHEOLOGY; CURING KINETICS; MOLECULAR ARCHITECTURE;

D O I：

10.1002/pola.1993.080310304

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A model two-step synthesis of a saturated hyperbranched hydroxyl-terminated ester has been developed to show a synthesis route. Three different series of hyperbranched esters with different terminations have been synthesized to relate some of their properties to their structures. This route has then been used to synthesize three different allyl ether-maleate functional hyperbranched ester resins in a two-step procedure. The resins have been characterized with respect to rheology, structure, and properties, and the differences are discussed. The allyl ether-maleate functional resins have also been studied with respect to curing performance and final film properties.

引用

页码：619 / 624

页数：6

共 14 条

[1] PREPARATION OF POLYMERS WITH CONTROLLED MOLECULAR ARCHITECTURE - A NEW CONVERGENT APPROACH TO DENDRITIC MACROMOLECULES [J].