NEUTRAL COMPLEXES OF GALLIUM DIIODIDE CONTAINING GA-GA BONDS

被引：9
|
作者：
BEAMISH, JC [1 ]
BOARDMAN, A [1 ]
WORRALL, IJ [1 ]
机构：
[1] UNIV LANCASTER,DEPT CHEM,LANCASTER LA1 4YA,ENGLAND
来源：
POLYHEDRON | 1991年 / 10卷 / 01期
关键词：
D O I：
10.1016/S0277-5387(00)83553-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes Ga2I4.2L (L = pyridine, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, morpholine, N-methylmorpholine, 1,4-dioxan, tetrahydrofuran, tetrahydropyran, dimethylsulphide, diethylsulphide, tetrahydrothiophene, 1,4-thioxan, 1,4-dithiane and tetramethylbiphosphine) have been prepared. Vibrational spectra indicate that the complexes adopt disubstituted ethane-like structures containing Ga-Ga bonds. We were unable to synthesize complexes of stoichiometry Ga2I4.4L which had previously been reported.
引用
收藏
页码：95 / 99
页数：5
相关论文
共 50 条
  • [41] (Ga-Ga)模型最佳样本容量确定方法
    杨艳秋
    刘洋萍
    宋立新
    吉林师范大学学报(自然科学版), 2014, 35 (02) : 40 - 42
  • [42] COMPLEXES CONTAINING INDIUM-GALLIUM BONDS
    SINCLAIR, I
    WORRALL, IJ
    INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1981, 17 (9-12): : 279 - 282
  • [43] Ga2I2[C(SiMe3)3]2 -: an organogallium(II) halide containing a Ga-Ga single bond
    Uhl, W
    El-Hamdan, A
    Prött, M
    Spuhler, P
    Frenking, G
    DALTON TRANSACTIONS, 2003, (07) : 1360 - 1364
  • [44] Ga-C and Ga-Ga bond formation using a NON-ligated gallyl nucleophile
    Edwards, Megan
    Hicks, Jamie
    McManus, Caitilin
    Goicoechea, Jose M.
    Aldridge, Simon
    POLYHEDRON, 2023, 242
  • [45] Characterization of isolated Ga2 molecules by resonance Raman spectroscopy and variations of Ga-Ga bonding
    Himmel, HJ
    Gaertner, B
    CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (23) : 5936 - 5941
  • [46] REDUCTION OF A TETRAARYLDIGALLANE TO AFFORD A RADICAL-ANION WITH GA-GA MULTIPLE BONDING CHARACTER
    HE, XM
    BARTLETT, RA
    OLMSTEAD, MM
    RUHLANDTSENGE, K
    STURGEON, BE
    POWER, PP
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05): : 717 - 719
  • [47] Trimethylaminedichlorogallane (Cl2Ga center dot NMe(3))(2) with the Ga-Ga intermetallic bond
    Pashkov, AY
    Belsky, VK
    Bulychev, BM
    Zvukova, TM
    RUSSIAN CHEMICAL BULLETIN, 1996, 45 (08) : 1973 - 1976
  • [48] SPECIAL SILAZANE DERIVATIVES OF DIGALLANE(4) AND DIINDIANE(4) WITH GA-GA AND IN-IN BOND
    VEITH, M
    GOFFING, F
    BECKER, S
    HUCH, V
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 406 (1-2) : 105 - 118
  • [49] Ga-Ga bonding and tunnel framework in the new Zintl phase Ba3Ga4Sb5
    Park, SM
    Kim, SJ
    Kanatzidis, MG
    JOURNAL OF SOLID STATE CHEMISTRY, 2003, 175 (02) : 310 - 315
  • [50] Twofold insertion of isocyanides into the Ga-Ga bond of tetrakis[bis(trimethylsilyl)methyl]digallane(4)
    Uhl, W
    Hahn, I
    Schutz, U
    Pohl, S
    Saak, W
    Martens, J
    Manikowski, J
    CHEMISCHE BERICHTE, 1996, 129 (08) : 897 - 901
12345