NEUTRAL COMPLEXES OF GALLIUM DIIODIDE CONTAINING GA-GA BONDS

被引：9
|
作者：
BEAMISH, JC [1 ]
BOARDMAN, A [1 ]
WORRALL, IJ [1 ]
机构：
[1] UNIV LANCASTER,DEPT CHEM,LANCASTER LA1 4YA,ENGLAND
来源：
POLYHEDRON | 1991年 / 10卷 / 01期
关键词：
D O I：
10.1016/S0277-5387(00)83553-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes Ga2I4.2L (L = pyridine, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, morpholine, N-methylmorpholine, 1,4-dioxan, tetrahydrofuran, tetrahydropyran, dimethylsulphide, diethylsulphide, tetrahydrothiophene, 1,4-thioxan, 1,4-dithiane and tetramethylbiphosphine) have been prepared. Vibrational spectra indicate that the complexes adopt disubstituted ethane-like structures containing Ga-Ga bonds. We were unable to synthesize complexes of stoichiometry Ga2I4.4L which had previously been reported.
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收藏
页码：95 / 99
页数：5
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