NEUTRAL COMPLEXES OF GALLIUM DIIODIDE CONTAINING GA-GA BONDS

被引：9

作者：

BEAMISH, JC ^{[1
]}

BOARDMAN, A ^{[1
]}

WORRALL, IJ ^{[1
]}

机构：

[1] UNIV LANCASTER,DEPT CHEM,LANCASTER LA1 4YA,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83553-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes Ga2I4.2L (L = pyridine, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, morpholine, N-methylmorpholine, 1,4-dioxan, tetrahydrofuran, tetrahydropyran, dimethylsulphide, diethylsulphide, tetrahydrothiophene, 1,4-thioxan, 1,4-dithiane and tetramethylbiphosphine) have been prepared. Vibrational spectra indicate that the complexes adopt disubstituted ethane-like structures containing Ga-Ga bonds. We were unable to synthesize complexes of stoichiometry Ga2I4.4L which had previously been reported.

引用

页码：95 / 99

页数：5

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