FORMATION OF EXOCYCLIC OLEFINIC GROUPS VIA STEREOSELECTIVE NITROSATIONS - A NEW ROUTE TOWARDS PENDANT ARM MACROCYCLIC LIGANDS

被引：7

作者：

BERNHARDT, PV ^{[1
]}

COMBA, P ^{[1
]}

机构：

[1] UNIV BASEL,INST ANORGAN CHEM,SPITALSTR 51,CH-4056 BASEL,SWITZERLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000113

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitrosation of the Cu(II) and Pd(II) complexes of trans-6,13-dimethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine results in new macrocyclic complexes bearing exclusively exocyclic olefinic groups as shown by an X-ray crystal structure and NMR spectroscopy.

引用

页码：113 / 114

页数：2

共 6 条

[1] COORDINATION OF 6,13-DIMETHYL-1,4,8,11-TETRA-AZACYCLOTETRADECANE-6,13-DIAMINE TO PLATINUM(II) AND PALLADIUM(II) - SYNTHESES, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURES OF THE PERCHLORATE SALTS OF BOTH COMPLEXES [J].

BERNHARDT, PV ;

LAWRANCE, GA ;

PATALINGHUG, WC ;

SKELTON, BW ;

WHITE, AH ;

CURTIS, NF ;

SIRIWARDENA, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (09) :2853-2858

[2] ISOLATION AND COMPLEXATION OF THE CIS ISOMER OF THE PENDANT ARM MACROCYCLE 6,13-DIMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE-6,13-DIAMINE [J].

BERNHARDT, PV ;

COMBA, P ;

HAMBLEY, TW ;

LAWRANCE, GA ;

VARNAGY, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (03) :355-359

[3] COMPLEXES OF POLYAZA MACROCYCLES BEARING PENDENT COORDINATING GROUPS [J].

BERNHARDT, PV ;

LAWRANCE, GA .

COORDINATION CHEMISTRY REVIEWS, 1990, 104 (02) :297-343

[4] REACTIONS OF PRIMARY ALIPHATIC AMINES WITH NITROUS ACID [J].

COLLINS, CJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1971, 4 (09) :315-&

[5] METAL-ION ENCAPSULATION - COBALT CAGES DERIVED FROM POLYAMINES, FORMALDEHYDE, AND NITROMETHANE [J].

GEUE, RJ ;

HAMBLEY, TW ;

HARROWFIELD, JM ;

SARGESON, AM ;

SNOW, MR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (19) :5478-5488

[6]

MARCH J, 1985, ADV ORGANIC CHEM

← 1 →