CRYSTAL-STRUCTURE OF NEW COMPOSITION BORON-RICH BORON-NITRIDE USING RAMAN-SPECTROSCOPY

被引：28

作者：

SAITOH, H ^{[1
]}

YOSHIDA, K ^{[1
]}

YARBROUGH, WA ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT MAT SCI & ENGN,UNIV PK,PA 16802

来源：

JOURNAL OF MATERIALS RESEARCH | 1993年 / 8卷 / 01期

关键词：

D O I：

10.1557/JMR.1993.0008

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis of polycrystalline boron nitride films, with beta-rhombohedral boron crystallites, was accomplished with BCl3-NH3-H-2 in a tungsten hot filament chemical vapor deposition apparatus. Raman spectra and XRD results revealed that the crystal structure of the boron nitride films is similar to rhombohedral boron carbide B4C. The composition of these crystallites by XPS was found to give a ratio of boron to nitrogen of 3:1. These results suggest that the boron nitride crystals obtained in this work are previously unreported compounds of a rhombohedral boron-rich boron nitride, analogous to boron carbide, B4C.

引用

页码：8 / 11

页数：4

共 20 条

[1]

ALESHIN VG, 1985, SVERKHTVERDYE MAT, V7, P12

[2] THE SOLID SOLUTION SERIES, BORON BORON CARBIDE [J].