ACTIVATION OF MOLECULAR-HYDROGEN BY TRANSITION-METAL COMPLEXES .2. FORMATION OF COMPLEXES OF PALLADIUM (0) AND (+1) WITH A METAL-METAL BOND DURING HYDROGENOLYSIS OF [PH3PPD(OAC)2]2

被引：0

作者：

BERENBLYUM, AS ^{[1
]}

KNIZHNIK, AG ^{[1
]}

MUND, SL ^{[1
]}

MOISEEV, II ^{[1
]}

机构：

[1] ALL UNION PETR PROC RES INST,ELEKTROGORSK,USSR

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 08期

关键词：

D O I：

10.1007/BF00950966

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of dipalladium μ-diacetatediacetatoditriphenylphosphine [Ph3PPd(OAc)2]2 with hydrogen leads to formation of complexes of Pd(0), (Ph3P)2Pd2, and of Pd(+l), (Ph3PPd(OAc)2, with a metal-metal bond. © 1980 Plenum Publishing Corporation.

引用

页码：1557 / 1559

页数：3

共 7 条

[1]

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[2]

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[4] REACTIONS OF SODIUM TETRAHYDROBORATE AND CYANOTRIHYDROBORATE WITH DIVALENT CO, NI, CU, PD, AND PT CHLORIDES IN PRESENCE OF TERTIARY PHOSPHINES [J].

HOLAH, DG ;

HUGHES, AN ;

HUI, BC ;

WRIGHT, K .

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[5]

LAKHMAN LI, 1977, THESIS MOSCOW

[6] ACETATO COMPLEXES OF PALLADIUM(2) [J].

STEPHENSON, TA ;

WILKINSON, G .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1967, 29 (08) :2122-+

[7]

VARGAFTIK MN, 1978, IZV AKAD NAUK SSSR K, P720

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