SELENIUM-CATALYZED NONRADICAL CHLORINATION OF OLEFINS WITH N-CHLOROSUCCINIMIDE

被引：66

作者：

HORI, T ^{[1
]}

SHARPLESS, KB ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 23期

关键词：

D O I：

10.1021/jo01337a046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Arylselenenyl chlorides (ArSeCl) or aryl di-selenides (ArSeSeAr) were effective as catalysts for the chlorination of olefins with N-chlorosuccinimide. The principal product is a rearranged allylic chloride, and the vinyl chloride is usually a minor product. Another method for nonradical allylic chlorination of olefins involves reaction of the olefin with TsN―S―O and N-chloro-succinimide and affords the unrearranged allylic chloride as the major product. © 1979, American Chemical Society. All rights reserved.

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页码：4204 / 4208

页数：5

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