SYNTHETIC AND STRUCTURAL CHARACTERIZATION OF METAL-COMPLEXES OF FERROCENYLACETYLENE - NOVEL DONOR-ACCEPTOR HETEROBIMETALLIC MATERIALS

被引：53
作者：
COLBERT, MCB [1 ]
INGHAM, SL [1 ]
LEWIS, J [1 ]
LONG, NJ [1 ]
RAITHBY, PR [1 ]
机构：
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 14期
关键词：
D O I：
10.1039/dt9940002215
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5){C5H4C=C[Os(dppm)2Cl]}] [dppm = 1,2-bis(diphenylphosphino)-methane] has been determined; their solution redox chemistry indicated metal-metal interaction via the conjugated ligand group.
引用
收藏
页码：2215 / 2216
页数：2
相关论文
共 20 条
  • [1] RIGID-ROD SIGMA-ACETYLIDE COMPLEXES OF IRON, RUTHENIUM AND OSMIUM
    ATHERTON, Z
    FAULKNER, CW
    INGHAM, SL
    KAKKAR, AK
    KHAN, MS
    LEWIS, J
    LONG, NJ
    RAITHBY, PR
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 462 (1-2) : 265 - 270
  • [2] SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF 2-DICYANOMETHYLENE-1,3-BIS(FERROCENYLMETHYL)-1,3-DIAZOLIDINE
    BENITO, A
    CANO, J
    MARTINEZMANEZ, R
    PAYA, J
    SOTO, J
    JULVE, M
    LLORET, F
    MARCOS, MD
    SINN, E
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (13): : 1999 - 2003
  • [3] BUTLER IR, 1992, ORGANOMETALLIC CHEM, V21, P338
  • [4] MOLECULAR 2ND-ORDER OPTICAL NONLINEARITIES OF METALLOCENES
    CALABRESE, JC
    CHENG, LT
    GREEN, JC
    MARDER, SR
    TAM, W
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) : 7227 - 7232
  • [5] SOME COMPLEXES OF TERTIARY PHOSPHINES WITH RUTHENIUM(II) AND OSMIUM(II)
    CHATT, J
    HAYTER, RG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (MAR): : 896 - &
  • [6] CHI KM, 1991, ORGANOMETALLICS, V10, P668
  • [7] SANDWICHES BRING A NEW ELEMENT TO MOLECULAR RECOGNITION
    CONSTABLE, EC
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04): : 407 - 408
  • [8] DOISNEAU G, 1992, J ORGANOMET CHEM, V425, P113, DOI 10.1016/0022-328X(92)80026-T
  • [9] 2ND-HARMONIC GENERATION IN TRANSITION-METAL ORGANIC-COMPOUNDS
    FRAZIER, CC
    HARVEY, MA
    COCKERHAM, MP
    HAND, HM
    CHAUCHARD, EA
    LEE, CH
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (22) : 5703 - 5706
  • [10] SYNTHESIS AND STRUCTURE OF (CIS)-[1-FERROCENYL-2-(4-NITROPHENYL)ETHYLENE], AN ORGANOTRANSITION METAL COMPOUND WITH A LARGE 2ND-ORDER OPTICAL NONLINEARITY
    GREEN, MLH
    MARDER, SR
    THOMPSON, ME
    BANDY, JA
    BLOOR, D
    KOLINSKY, PV
    JONES, RJ
    [J]. NATURE, 1987, 330 (6146) : 360 - 362
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