TRICYCLIC ETHERS FROM FISCHER VINYLCARBENE COMPLEXES AND BETA-OXYGEN-FUNCTIONALIZED ORGANOLITHIUM COMPOUNDS

被引：25
作者：
BARLUENGA, J
MONTSERRAT, JM
FLOREZ, J
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期
关键词：
D O I：
10.1039/c39930001068
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A one-pot synthesis of tricyclic ring systems has been achieved by the Michael addition of beta-oxygen-functionalized organolithium compounds to Fischer vinylcarbene complexes followed by an intramolecular alkoxide exchange and intramolecular cyclopropanation reaction.
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收藏
页码：1068 / 1070
页数：3
相关论文
共 34 条
[1]   A PROTECTIVE STRATEGY IN CARBENE COMPLEX CHEMISTRY - SYNTHESIS OF FUNCTIONALIZED FISCHER CARBENE COMPLEXES VIA DIANION FORMATION [J].
AOKI, S ;
FUJIMURA, T ;
NAKAMURA, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (08) :2985-2990
[2]   ORGANIC SYNTHESES VIA TRANSITION-METAL COMPLEXES .2. 1-CHROMA-1,3-BUTADIENES AND 1-CHROMA-1,3,5-HEXATRIENES FROM (CO)5CR=C(OC2H5)CH3 BY CARBONYL OLEFINATION CATALYZED WITH TRIETHYLAMINE CHLOROTRIMETHYLSILANE [J].
AUMANN, R ;
HEINEN, H .
CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (04) :537-540
[3]   BETA-SUBSTITUTED ORGANO-LITHIUM COMPOUNDS - DIRECT PREPARATION AND REACTIVITY [J].
BARLUENGA, J ;
FLOREZ, J ;
YUS, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (20) :1153-1154
[4]   CHLOROMETHYL-LITHIUM AND 1-CHLORO-2-METHYLPROP-1-ENYL-LITHIUM - USEFUL INTERMEDIATES IN THE SYNTHESIS OF UNSATURATED AND BIFUNCTIONALIZED COMPOUNDS [J].
BARLUENGA, J ;
FERNANDEZSIMON, JL ;
CONCELLON, JM ;
YUS, M .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (12) :3339-3343
[5]   BETA-SUBSTITUTED ORGANO-LITHIUM COMPOUNDS - NEW REAGENTS FOR SYNTHESIS [J].
BARLUENGA, J ;
FANANAS, FJ ;
YUS, M .
JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (26) :4798-4801
[6]   BETA-SUBSTITUTED ORGANO-LITHIUM COMPOUNDS FROM CHLOROHYDRINS - APPLICATION TO THE DIRECT SYNTHESIS OF BIFUNCTIONALIZED ORGANIC-COMPOUNDS [J].
BARLUENGA, J ;
FLOREZ, J ;
YUS, M .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1983, (12) :3019-3026
[7]   ORGANOMETALLIC DERIVATIVES OF EPOXIDES [J].
BARTMANN, E .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (07) :653-654
[8]   SYNTHESIS OF A CHELATED TUNGSTEN CARBENE ALKENE COMPLEX AND ITS CONVERSION TO A CYCLOPROPANE [J].
CASEY, CP ;
VOLLENDORF, NW ;
HALLER, KJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (13) :3754-3764
[9]   INTRAMOLECULAR CYCLOPROPANATION AND OLEFIN METATHESIS REACTIONS OF (CO)5W=C(OCH2CH2CH=CHOCH3)C6H4-PARA-CH3 [J].
CASEY, CP ;
HORNUNG, NL ;
KOSAR, WP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) :4908-4916
[10]   SYNTHESIS AND CRYSTAL-STRUCTURE OF DIPHENYLCARBENE(PENTACARBONYL)TUNGSTEN(0) [J].
CASEY, CP ;
BURKHARDT, TJ ;
BUNNELL, CA ;
CALABRESE, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) :2127-2134
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