UNUSUAL STABILIZATION OF TRANS-2,2'-BIPYRIDINE LIGANDS IN A RHENIUM(V) PHENYLIMIDO COMPLEX

被引：35

作者：

BAKIR, M ^{[1
]}

PAULSON, S ^{[1
]}

GOODSON, P ^{[1
]}

SULLIVAN, BP ^{[1
]}

机构：

[1] UNIV WYOMING,DEPT CHEM,LARAMIE,WY 82071

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 07期

关键词：

D O I：

10.1021/ic00033a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trans-PhNRe(bpy)2(OEt)2+ (bpy = 2,2'-bipyridine) is thermally stable despite severe steric interactions between the mutually trans bpy ligands; an X-ray diffraction study reveals axial multiple bonding involving the N-Re-OEt framework that is key to understanding this observation.

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收藏

页码：1127 / 1129

页数：3

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