METAL-ION COMPLEX-FORMATION OF POLY(OXYETHYLENE) WITH 5-CHLORO-8-QUINOLINOXYL END-GROUPS

被引：25

作者：

ANGELOVA, N ^{[1
]}

MANOLOVA, N ^{[1
]}

RASHKOV, I ^{[1
]}

机构：

[1] BULGARIAN ACAD SCI,INST POLYMER,BU-1113 SOFIA,BULGARIA

来源：

EUROPEAN POLYMER JOURNAL | 1995年 / 31卷 / 08期

关键词：

D O I：

10.1016/0014-3057(95)00024-0

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Complex formation between alpha-(5-chloro-8-quinolinoxy)-omega -(5-chloro-8-quinolinyl)poly (oxyethylene) (POE*) and Fe3+ ions as well as the formation of interpolymer complexes between POE* and polyacrylic acid (PAA) in the presence of Fe3+ were studied. The complexes were characterized by u.v.-vis spectroscopy. The stoichiometry and stability constants of the complexes were determined from changes in absorption due to complexation of the quinolinoxy groups of POE* with Fe3+.

引用

页码：741 / 748

页数：8

共 18 条

[1]

ALBERT A, 1971, SELECTIVE TOXICITY

[2] EINE NEUE METHODE ZUR ERMITTLUNG DER ZUSAMMENSETZUNG SCHWACHER KOMPLEXE [J].

ASMUS, E ;

HINZ, U ;

OHLS, K ;

RICHLY, W .

FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1960, 178 (02) :104-116

[3] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].

BENESI, HA ;

HILDEBRAND, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707

[4] POLYMER COMPLEXES .15. THERMAL-STABILITY OF POLY(ETHYLENE GLYCOL) HOMOPOLYMER AND POLYMER COMPLEXES OF POLY(ETHYLENE GLYCOL) WITH SOME TRANSITION-METAL CHLORIDES [J].

DIAB, MA ;

ELSONBATI, AZ .

POLYMER DEGRADATION AND STABILITY, 1990, 29 (03) :271-277

[5] THE STABILITY AND LIGHT ABSORPTION OF THE COMPLEX ION FESCN++ [J].

FRANK, HS ;

OSWALT, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (06) :1321-1325

[6]

Hollingshead R.G.W., 1954, OXINE ITS DERIVATIVE

[7]

LUNBERG RG, 1966, J POLYM SCI POL CHEM, V4, P1563

[8] COORDINATION-COMPLEXES BETWEEN IRON(III) CHLORIDE AND POLYETHER, POLYESTER, AND POLY(ETHER ESTER) [J].

RABEK, JF ;

LUCKI, J ;

QU, BJ ;

SHI, WF .

MACROMOLECULES, 1991, 24 (04) :836-843

[9] PREPARATION AND PROPERTIES OF POLY(OXYETHYLENE)S WITH 5-CHLORO-8-QUINOLINOXYL END-GROUPS [J].

RASHKOV, I ;

ANGELOVA, N ;

MANOLOVA, N .

EUROPEAN POLYMER JOURNAL, 1993, 29 (11) :1407-1417

[10]

RASHKOV I, 1990, COMMUN DEP CHEM BULG, V23, P465

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