REACTION OF ALKYNE HAVING HYDROXYPHENYL GROUP WITH MO(CO)(6)

被引:53
作者
KANETA, N
HIRAI, T
MORI, M
机构
[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN
[2] OSAKA CITY UNIV,FAC SCI,OSAKA 558,JAPAN
关键词
D O I
10.1246/cl.1995.627
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of m-and p-hydroxyphenylpropyne, 1a and 1b, with Mo(CO)(6) (5 mol%) affords metathesis products, 2a and 2b, in 78% and 14% (conversion yield, 78%) yields, respectively. However, o-hydroxyphenylpropyne 1f gave trimerization product 4 in 65% yield.
引用
收藏
页码:627 / 628
页数:2
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