IONIC MOBILITY - THEORY MEETS EXPERIMENT

被引：95

作者：

EVANS, DF ^{[1
]}

TOMINAGA, T ^{[1
]}

HUBBARD, JB ^{[1
]}

WOLYNES, PG ^{[1
]}

机构：

[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 20期

关键词：

D O I：

10.1021/j100483a025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two recent theories for ionic mobility, the Hubbard-Onsager theory which is based on a continuum model and the Wolynes theory which is based on a stochastic model, are critically tested by comparison with conductance data. Both theories predict finite mobilities as the ionic size decreases and thus can successfully account for many of the observed features of conductance data. The models upon which the theories are based are described in detail and the current state of ionic mobility theory is discussed. © 1979 American Chemical Society.

引用

页码：2669 / 2677

页数：9

共 23 条

[1] VAN DER WAALS VOLUMES + RADII [J].