Bis(2,2 '-bipyridyl-kappa N-2,N ')bis-(dicyanamido-kappa N)manganese(II)

被引:3
作者
Wang, Haixia [1 ]
Wang, Shaohong [1 ]
Lang, Yuehe [1 ]
机构
[1] Henan Normal Univ, Dept Chem & Environm Sci, Xinxiang 453007, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
D O I
10.1107/S1600536812014183
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In title complex, [Mn(C2N3)(2)(C10H8N2)(2)], the Mn-II ion is coordinated in a slightly distorted octahedral geometry by six N atoms. Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands. The dihedral angle formed by the mean planes of the bipyridine rings is 85.93 (14)degrees. The central N atom of one of the dicyanamide ligands was refined as disordered over two sites with equal occupancies.
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页码:M569 / +
页数:8
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