4-[5-(Furan-2-yl)-3-trifluoromethyl-1H-pyrazol-1-yl]benzenesulfonamid

被引:2
作者
Asiri, Abdullah M. [1 ,2 ]
Faidallah, Hassan M. [1 ]
Alamry, Khalid A. [1 ]
Ng, Seik Weng [1 ,3 ]
Tiekink, Edward R. T. [3 ]
机构
[1] King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah 80203, Saudi Arabia
[2] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah, Saudi Arabia
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
D O I
10.1107/S1600536812011920
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C14H10F3N3O3S, there are significant twists in the molecule, as seen in the values of the dihedral angles between the pyrazole ring and each of the furan [31.1 (2)degrees] and benzene rings [55.58 (10)degrees]. The amino N atom occupies a position almost normal to the benzene ring [NS- C-ar-C-ar (ar = aromatic) torsion angle = 83.70 (19)degrees]. One amino H atom forms a hydrogen bond to the tricoordinate pyrazole N atom and the other interacts with a sulfonamide O atom, forming a supramolecular chain along [010]. The chains are consolidated into a supramolecular layers via C - H center dot center dot center dot O interactions involving the second sulfonamide O atom; layers stack along [10 (1) over bar]. The furan ring was found to be disordered over two diagonally opposite orientations of equal occupancy.
引用
收藏
页码:O1168 / +
页数:11
相关论文
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