2-DEOXYCHAMAEDROXIDE, A NEOCLERODANE DITERPENOID FROM TEUCRIUM-DIVARICATUM

被引：15
作者：
BRUNO, M
PIOZZI, F
SAVONA, G
RODRIGUEZ, B
DELATORRE, MC
SERVETTAZ, O
机构：
[1] CSIC, INST QUIM ORGAN, E-28006 MADRID, SPAIN
[2] UNIV MILAN, DEPARTIMENTO BIOL, I-20122 MILAN, ITALY
来源：
PHYTOCHEMISTRY | 1987年 / 26卷 / 10期
关键词：
D O I：
10.1016/S0031-9422(00)83609-2
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A new neo-clerodane diterpenoid, 2-deoxychamaedroxide, has been isolated from the aerial parts of Teucrium divaricatum subsp. canescens. Also identified were the previously known diterpenoids teuflin, teucrin H2, teuflidin, teucrins A, F and G, 6.beta.-hydroxy-teuscordin, montanin D and dihydroteugin. The structure of 2-deoxychamaedroxide, (12S)-47b,6.beta.; 15,16-diepoxy-neo-clerodane-13(16),14-diene-18,19;20,12-diolide, was established mainly by spectroscopic means.
引用
收藏
页码：2859 / 2861
页数：3
相关论文
共 15 条
[1]   NEW NEOCLERODANE DITERPENOID CONTAINING AN OXETANE RING ISOLATED FROM TEUCRIUM-CHAMAEDRYS - X-RAY STRUCTURE DETERMINATION [J].
EGUREN, L ;
PERALES, A ;
FAYOS, J ;
RODRIGUEZ, B ;
SAVONA, G ;
PIOZZI, F .
JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (21) :4157-4160
[2]   TEUCRINS H1-H4, NOVEL CLERODANE-TYPE DITERPENES FROM TEUCRIUM-HYRACANICUM [J].
GACSBAITZ, E ;
RADICS, L ;
OGANESSIAN, GB ;
MNATSAKANIAN, VA .
PHYTOCHEMISTRY, 1978, 17 (11) :1967-1973
[3]   MONTANIN-D, A NEW FURANOID DITERPENE OF CLERODANE TYPE FROM TEUCRIUM-MONTANUM L [J].
MALAKOV, PY ;
PAPANOV, GY ;
MOLLOV, NM ;
SPASSOV, SL .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (10) :1142-1144
[4]  
PAPANOV GY, 1982, Z NATURFORSCH B, V37, P519
[5]   THE C-12 AND C-20 CONFIGURATIONS OF SOME NEOCLERODANE DITERPENOIDS ISOLATED FROM TEUCRIUM SPECIES [J].
PASCUAL, C ;
FERNANDEZ, P ;
GARCIAALVAREZ, MC ;
MARCO, JL ;
FERNANDEZGADEA, F ;
DELATORRE, MC ;
HUESORODRIGUEZ, JA ;
RODRIGUEZ, B ;
BRUNO, M ;
PATERNOSTRO, M ;
PIOZZI, F ;
SAVONA, G .
PHYTOCHEMISTRY, 1986, 25 (03) :715-718
[6]  
PIOZZI F, 1987, HETEROCYCLES, V25, P807
[7]  
POPA DP, 1974, KHIM PRIR SOEDIN+, P321
[8]  
REINBOLD AM, 1974, KHIM PRIR SOEDIN+, P589
[9]   ISOTEUFLIDIN, A NEO-CLERODANE DITERPENOID FROM TEUCRIUM-CHAMAEDRYS, AND REVISED STRUCTURES OF TEUCRIN-F AND TEUCRIN-G [J].
RODRIGUEZ, MC ;
BARLUENGA, J ;
SAVONA, G ;
PIOZZI, F ;
SERVETTAZ, O ;
RODRIGUEZ, B .
PHYTOCHEMISTRY, 1984, 23 (07) :1465-1469
[10]   NEO-CLERODANE DITERPENOIDS FROM TEUCRIUM-CHAMAEDRYS - THE IDENTITY OF TEUCRIN-B WITH DIHYDROTEUGIN [J].
RODRIGUEZ, MC ;
BARLUENGA, J ;
PASCUAL, C ;
RODRIGUEZ, B ;
SAVONA, G ;
PIOZZI, F .
PHYTOCHEMISTRY, 1984, 23 (12) :2960-2961
12