OPTICAL-ACTIVITY OF CHIRAL DENDRITIC SURFACES

被引：108
作者：
JANSEN, JFGA
PEERLINGS, HWI
DEBRABANDERVANDENBERG, EMM
MEIJER, EW
机构：
[1] EINDHOVEN UNIV TECHNOL,ORGAN CHEM LAB,5600 MB EINDHOVEN,NETHERLANDS
[2] DSM RES BV,6160 MD GELEEN,NETHERLANDS
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期
关键词：
CHIRALITY; CHIROPTICAL STUDIES; CIRCULAR DICHROISM; DENDRIMERS; STEREOCHEMISTRY;
D O I：
10.1002/anie.199512061
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The optical rotation of poly(propylene imine) dendrimers with 64 identical enantiomerically pure amino acid end groups tends to zero. This remarkable behavior results from the packing of the end groups in the highly dense, multiply hydrogenbonded surface, which gives rise to different frozen‐in conformations, leading to an internal compensation of optical activity. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码：1206 / 1209
页数：4
相关论文
共 50 条
[21]  
KITAMURA M, 1991, ANGEW CHEM, V103, P34
[22]   UNIQUE PROPERTIES OF CHROMOPHORE-CONTAINING BILAYER AGGREGATES - ENHANCED CHIRALITY AND PHOTOCHEMICALLY INDUCED MORPHOLOGICAL CHANGE [J].
KUNITAKE, T ;
NAKASHIMA, N ;
SHIMOMURA, M ;
OKAHATA, Y ;
KANO, K ;
OGAWA, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (21) :6642-6644
[23]   CHIRAL, SYNTHETIC BILAYER MEMBRANES [J].
KUNITAKE, T ;
NAKASHIMA, N ;
HAYASHIDA, S ;
YONEMORI, K .
CHEMISTRY LETTERS, 1979, (11) :1413-1416
[24]  
Lehn J. M., 1988, ANGEW CHEM, V100, P91, DOI DOI 10.1002/ANGE.19881000110
[25]   SUPRAMOLECULAR CHEMISTRY - SCOPE AND PERSPECTIVES MOLECULES, SUPERMOLECULES, AND MOLECULAR DEVICES [J].
LEHN, JM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (01) :89-112
[26]   CONFORMATIONAL FREE-ENERGIES FROM SIMULATION - STOCHASTIC DYNAMICS MONTE-CARLO SIMULATIONS OF A HOMOLOGOUS SERIES OF GELLMANS DIAMIDES [J].
MCDONALD, DQ ;
STILL, WC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (25) :11550-11553
[27]   DENDRITIC ANALOGS OF ENGINEERING PLASTICS - A GENERAL ONE-STEP SYNTHESIS OF DENDRITIC POLYARYL ETHERS [J].
MILLER, TM ;
NEENAN, TX ;
KWOCK, EW ;
STEIN, SM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (01) :356-357
[28]  
MISLOW K, 1994, B SOC CHIM FR, V131, P534
[29]   A TOPOLOGICALLY CHIRAL [2]CATENAND [J].
MITCHELL, DK ;
SAUVAGE, JP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (07) :930-931
[30]   UNUSUALLY LARGE INDUCED CIRCULAR-DICHROISM OF AN AROMATIC COMPOUND BOUND TO HELICAL SUPERSTRUCTURES OF CHIRAL AMMONIUM BILAYERS [J].
NAKASHIMA, N ;
ANDO, R ;
MURAMATSU, T ;
KUNITAKE, T .
LANGMUIR, 1994, 10 (01) :232-234
12345