OPTICAL-ACTIVITY OF CHIRAL DENDRITIC SURFACES

被引：108
作者：
JANSEN, JFGA
PEERLINGS, HWI
DEBRABANDERVANDENBERG, EMM
MEIJER, EW
机构：
[1] EINDHOVEN UNIV TECHNOL,ORGAN CHEM LAB,5600 MB EINDHOVEN,NETHERLANDS
[2] DSM RES BV,6160 MD GELEEN,NETHERLANDS
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期
关键词：
CHIRALITY; CHIROPTICAL STUDIES; CIRCULAR DICHROISM; DENDRIMERS; STEREOCHEMISTRY;
D O I：
10.1002/anie.199512061
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The optical rotation of poly(propylene imine) dendrimers with 64 identical enantiomerically pure amino acid end groups tends to zero. This remarkable behavior results from the packing of the end groups in the highly dense, multiply hydrogenbonded surface, which gives rise to different frozen‐in conformations, leading to an internal compensation of optical activity. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：1206 / 1209
页数：4
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