REACTION OF C-60 AND C-70 WITH OZONE AT DIFFERENT TEMPERATURES

被引：0

作者：

HEYMANN, D ^{[1
]}

CHIBANTE, LPF ^{[1
]}

机构：

[1] RICE UNIV,DEPT CHEM,HOUSTON,TX 77251

来源：

RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY | 1993年 / 112卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of C60 and C70, dissolved in toluene, with ozone at 100, 23.5, 0, - 16, and - 78-degrees-C are reported. Both fullerenes are transformed swiftly at all of these temperatures. Both fullerenes form monoxides, dioxides and possibly higher oxides. The ratio of the rate parameters for the transformations of the two fullerenes change only slightly in the above temperature range. C60, however, is transformed about 40% faster than C70. The maximum yields of C60O, C60O2 and C70O increase at higher temperature.

引用

页码：531 / 534

页数：4

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