OXIDATIVE ADDITION OF DICHLOROMETHANE TO [(DPPE)RH]2(MU-CL)2 (DPPE = PH2PCH2CH2PPH2) - X-RAY STRUCTURE OF [(DPPE)RHCL]2(MU-CL)2(MU-CH2)

被引:49
作者
BALL, GE [1 ]
CULLEN, WR [1 ]
FRYZUK, MD [1 ]
JAMES, BR [1 ]
RETTIG, SJ [1 ]
机构
[1] UNIV BRITISH COLUMBIA,DEPT CHEM,2036 MAIN MALL,VANCOUVER V6T 1Z1,BC,CANADA
关键词
D O I
10.1021/om00056a058
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dichloromethane reacts with the rhodium chloride-bridged dimer [(dppe)Rh]2(mu-Cl)2, where dppe = Ph2PCH2CH2PPh2, to generate the bridging-methylene derivative [(dppe)RhCl]2(mu-Cl)2(mu-CH2).
引用
收藏
页码:3767 / 3769
页数:3
相关论文
共 16 条