OXIDATIVE ADDITION OF DICHLOROMETHANE TO [(DPPE)RH]2(MU-CL)2 (DPPE = PH2PCH2CH2PPH2) - X-RAY STRUCTURE OF [(DPPE)RHCL]2(MU-CL)2(MU-CH2)

被引：49

作者：

BALL, GE ^{[1
]}

CULLEN, WR ^{[1
]}

FRYZUK, MD ^{[1
]}

JAMES, BR ^{[1
]}

RETTIG, SJ ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,2036 MAIN MALL,VANCOUVER V6T 1Z1,BC,CANADA

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 10期

关键词：

D O I：

10.1021/om00056a058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dichloromethane reacts with the rhodium chloride-bridged dimer [(dppe)Rh]2(mu-Cl)2, where dppe = Ph2PCH2CH2PPh2, to generate the bridging-methylene derivative [(dppe)RhCl]2(mu-Cl)2(mu-CH2).

引用

页码：3767 / 3769

页数：3

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