SYNTHESIS AND STRUCTURE OF A HIGH-NUCLEARITY OXOMOLYBDENUM(V) COMPLEX, [(C5ME5RHIII)8(MO(V)12O36)(MO(VI)O4)]2+

被引：49
作者：
CHAE, HK
KLEMPERER, WG
LOYO, DEP
DAY, VW
EBERSPACHER, TA
机构：
[1] UNIV ILLINOIS,DEPT CHEM,URBANA,IL 61801
[2] UNIV ILLINOIS,MAT RES LAB,URBANA,IL 61801
[3] UNIV NEBRASKA,DEPT CHEM,LINCOLN,NE 68588
来源：
INORGANIC CHEMISTRY | 1992年 / 31卷 / 15期
关键词：
D O I：
10.1021/ic00041a003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrothermal treatment of MoO3.2H2O with [(C5Me5Rh)2(OH)3]Cl Yields a Cl-/OH- salt of the [(C5Me5Rh)8(Mo13O40)]2+ cation whose metal-oxygen framework is shown on the left. This species contains a central [(MOV12O36)(MOVIO4)]14- core having the [Al13O4(OH)24(H2O)12]7+ framework structure (epsilon-Keggin structure). This dodecanuclear oxomolybdenum (V) complex is comprised of six Mo-Mo dimers and shows for the first time that Mo(V) can form high-nuclearity polyoxoanions.
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页码：3187 / 3189
页数：3
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