SYNTHESIS OF THE PERFLUOROACETYLDIISOPROPYLMETHYL RADICAL

被引：7

作者：

AVETISYAN, EA ^{[1
]}

TUMANSKII, BL ^{[1
]}

CHERSTKOV, VF ^{[1
]}

STERLIN, SR ^{[1
]}

GERMAN, LS ^{[1
]}

机构：

[1] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1993年 / 42卷 / 01期

关键词：

RADICAL; PERFLUOROKETONE; SYNTHESIS; ESR;

D O I：

10.1007/BF00700014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stable trifluoroacetylperfluorodiisopropylmethyl radical has been prepared by interaction of the (alpha-fluomsulfonyloxytetrafluoroethyl)perfluorodiisopropylmethyl radical with anhydrous CsF. This reaction is the first example of a chemical transformation of a C-centered radical which is not resonance-stabilized with retention of the radical center.

引用

页码：207 / 208

页数：2

共 5 条

[1] Buchachenko A. L., 1973, STABLE RADICALS, P58
[2] CHERSTKOV VF, 1990, IAN SSSR KH, P2450
[3] F-2,4-DIMETHYL-3-ETHYL-3-PENTYL AND "F-2,4-DIMETHYL-3-ISOPROPYL-3-PENTYL - STABLE TERT-PERFLUOROALKYL RADICALS PREPARED BY ADDITION OF FLUORINE OR TRIFLUOROMETHYL TO A PERFLUOROALKENE
SCHERER, KV
ONO, T
YAMANOUCHI, K
FERNANDEZ, R
HENDERSON, P
GOLDWHITE, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (03) : 718 - 719
[4] ESR STUDY OF THE FREE-RADICALS FORMED IN THE PHOTOLYSIS OF ALPHA-KETOFLUOROSULFATES
TUMANSKII, BL
BUBNOV, NN
SOLODOVNIKOV, SP
CHERSTKOV, VF
STERLIN, SR
AVETISYAN, EA
ROGOVIK, VM
GERMAN, LS
[J]. BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE, 1992, 41 (03): : 594 - 596
[5] ZAPEVALOV AY, 1985, ZH ORG KHIM+, V21, P2113

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