SYNTHESIS AND PROPERTIES OF DOUBLE-CALIX[4]ARENES, DOUBLY-CROWNED CALIX[4]ARENES, AND DOUBLE-CALIX-CROWNS

被引：53

作者：

ASFARI, Z ^{[1
]}

WEISS, J ^{[1
]}

PAPPALARDO, S ^{[1
]}

VICENS, J ^{[1
]}

机构：

[1] UNIV CATANIA,DIPARTAMENTO SCI CHIM,I-95125 CATANIA,ITALY

来源：

PURE AND APPLIED CHEMISTRY | 1993年 / 65卷 / 03期

关键词：

D O I：

10.1351/pac199365030585

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses of double-calix[4]arenes, doubly-crowned calix[4]arenes, and double-calix-crowns have been achieved by reacting p-tert-butylcalix[4]arene or a new mesitol based calix[4]arene with various polyethylene glycol ditosylates in the presence of potassium carbonate in refluxing acetonitrile. Depending on the nature of the ditosylate and on the reaction times are differently obtained calixarene ligands. The complexation properties toward alkali cations are presented for the double-calix-crown derived of p-tert-butylcalix[4]arene.

引用

页码：585 / 590

页数：6

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