trans-Chloridobis(4-methylpyridine-kappa N)(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine-kappa(3) N,N',N'')ruthenium(II) hexafluoridophosphate acetone monosolvate

被引：0

作者：

Redford, Christopher ^{[1
]}

Gimbert-Surinach, Carolina ^{[1
]}

Bhadbhade, Mohan ^{[2
]}

Colbran, Stephen B. ^{[1
]}

机构：

[1] Univ New South Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Univ New South Wales, Mark Wainwright Analyt Ctr, Sydney, NSW 2052, Australia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

基金：

澳大利亚研究理事会;

关键词：

data-to-parameter ratio = 13.6; disorder in main residue; mean σ(C-C) = 0.010 Å; R factor = 0.059; single-crystal X-ray study; T = 156 K; wR factor = 0.171;

D O I：

10.1107/S1600536812005594

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [RuCl(C 6H 7N) 2(C 27H 35N 3)]PF 6·C 3H 6O, was obtained unintentionally as the product of the reaction of 1,1′-methylenebis(4-methylpyridinium) hexafluorisophosphate and RuCl3(tpy*) (tpy*is 4,4′,4″-tri-tert-butyl-2, 2′:6′,2″-terpyridine) in the presence of triethylamine and LiCl. The mol-ecular structure of the complex displays an octahedral geometry around the Ru II ion and the unit cell contains an acetone solvent molecule and one orientationally disordered PF 6 - anion (occupancy ratio 0.75:0.25) which is hydrogen bonded to two H atoms of the tpy*ligand of the nearest [RuCl(pic) 2(tpy*)] + cation (pic is 4-methylpyridine). One of the tertbutyl groups of the tpy*ligand is also disordered over two sets of sites in a 0.75:0.25 ratio.

引用

页码：M300 / U746

页数：13

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