FISCHER-TROPSCH SYNTHESIS ON RUTHENIUM SUPPORTED ETS-10 TITANIUM SILICATE CATALYSTS

被引：15
作者：
CARLI, R
BIANCHI, CL
RAGAINI, V
机构：
[1] Department of Physical Chemistry and Electrochemistry, University of Milan, Milan, 20133
来源：
CATALYSIS LETTERS | 1995年 / 33卷 / 1-2期
关键词：
FISCHER-TROPSCH SYNTHESIS; TITANIUM SILICATE MOLECULAR SIEVES; RUTHENIUM SUPPORTED CATALYSTS; OLEFINS READSORPTION;
D O I：
10.1007/BF00817045
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Titanium silicate ETS-10 was found to be a suitable metal catalyst support, having high surface area, high ion exchange capacity and no acidic functions. In this work, ETS-10 was used as a support in preparing ruthenium supported catalyst for Fischer-Tropsch synthesis. Ru/M-ETS-10 catalytic systems (M standing for Na or K) showed some important characteristics, as good metal dispersion and shape selectivity. Moreover, no side reactions due to acidic functions were evidenced; indeed readsorption of olefins on active metal centers was found to control the activity of the catalysts.
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页码：49 / 55
页数：7
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