VERSATILE BEHAVIOR OF O-STANNYLATED D-GLUCAL TOWARDS HALOGENS

被引：35

作者：

CZERNECKI, S ^{[1
]}

LETEUX, C ^{[1
]}

VEYRIERES, A ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM GLUCIDES LAB,4 PL JUSSIEU,F-75230 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 02期

关键词：

TRIBUTYLTIN ETHERS; D-GLUCAL; ALLYLIC OXIDATION; HALOCYCLIZATION; 3.2.1] BICYCLIC SYNTHONS;

D O I：

10.1016/0040-4039(92)88055-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

O-Tributylstannyl-D-glucal undergoes allylic oxidation when treated with N-iodosucinimide (NIS) in benzene, whereas oxidative 1,6-halocyclization occurs with NIS in acetonitrile or molecular halogens in various solvents.

引用

页码：221 / 224

页数：4

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