ON THE THEORY OF THE INTEGER AND HALF-INTEGER INTEGRAL AND DERIVATIVE LINEAR POTENTIAL SWEEP VOLTAMMETRY FOR A TOTALLY IRREVERSIBLE INTERFACIAL REACTION

The equations of the integer and half-integer integral and derivative of the current with respect to time and the equations of the half-wave potential in the integral voltammogram and the peak potentials in their semi-integral and derivative voltammograms were derived for a totally irreversible interfacial reaction when both the oxidized and the reduced forms are strongly adsorbed and a Langmuir isotherm is obeyed. These equations have been verified.