High-resolution study of the infrared band nu(2) of (CHCl3)-Cl-35

被引：0
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作者：
Paso, R
Horneman, VM
Pietila, J
Anttila, R
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来源：
CHEMICAL PHYSICS LETTERS | 1995年 / 247卷 / 03期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Fourier transform spectrum of the nu(2) band around 676 cm(-1) of isotopically pure (CHCl3)-Cl-35 has been measured. The experimental resolution was near 0.0010 cm(-1). In this parallel band more than 3000 rotational lines, with J(max) = 100 and K-max = 56, were assigned. In the analysis a model for an unperturbed symmetric top band was applied. The fit of 2852 lines, with a standard deviation of 0.17 x 10(-3) cm(-1), led, among others, to the following results: nu(0) = 676.643310(9) cm(-1), B-2 - B-0 = - 0.493903(6) x 10(-3) cm(-1) and C-2 - C-0 = - 0.109899(22) x 10(-3) cm(-1).
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页码：277 / 282
页数：6
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