THE REACTION OF COARSE-GRAIN MANGANESE POWDER WITH DIIODOTRIMETHYLPHOSPHORANE TO FORM [MN(PME3)I2]N, WHICH REACTS WITH TRACE QUANTITIES OF MOLECULAR-OXYGEN TO FORM THE MIXED (+2/+3) OXIDATION-STATE COMPLEX [MN2(PME3)3I5]PME3

被引：23
作者：
MCAULIFFE, CA
GODFREY, SM
MACKIE, AG
PRITCHARD, RG
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 06期
关键词：
D O I：
10.1039/c39920000483
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Coarse-grain unactivated manganese powder reacts with Me3Pl2 in diethyl ether to form the polymeric [Mn(PMe3)l2]n complex, I, which reacts with trace quantities of dioxygen to form dinuclear [Mn2(PMe3)3l5].PMe3, II, the first mixed oxidation state (+2/+3) manganese complex which contains phosphine ligands; both I and II react with an excess of dioxygen to form the monomeric [Mn(PMe3)2l3].
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页码：483 / 485
页数：3
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