Crystal structure of bis(benzylamine-kappa N)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-kappa N-4]iron(II) n-hexane monosolvate

被引：2
|
作者：
Dhifaoui, Selma [1 ]
Harhouri, Wafa [1 ]
Bujacz, Anna [2 ]
Nasri, Habib [1 ]
机构：
[1] Univ Monastir, Fac Sci Monastir, Lab Physicochim Mat, Ave Environm, Monastir 5019, Tunisia
[2] Lodz Univ Technol, Inst Tech Biochem, Xray Anal Lab, Stefanowskiego 4-10, PL-90924 Lodz, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
关键词：
crystal structure; hydrogen bonding; UV-vis spectra; iron(II)-porphyrin; benzylamine;
D O I：
10.1107/S2056989015024135
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Fe-II(C44H24Cl4N4)(C6H5CH2NH2)(2)]center dot C6H14 or [Fe-II(TPP-Cl)(BzNH(2))(2)]center dot n-hexane [where TPP-Cl and BzNH(2) are 5,10,15,20-tetrakis(4-chlorophenyl)porphyrinate and benzylamine ligands, respectively], the Fe-II cation lies on an inversion centre and is octahedrally coordinated by the four pyrrole N atoms of the porphyrin ligand in the equatorial plane and by two amine N atoms of the benzylamine ligand in the axial sites. The crystal structure also contains one inversion-symmetric n-hexane solvent molecule per complex molecule. The average Fe-N-pyrrole bond length [1.994 (3) angstrom] indicates a low-spin complex. The crystal packing is sustained by N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl hydrogen-bonding interactions and by C-H center dot center dot center dot pi intermolecular interactions, leading to a three-dimensional network structure.
引用
收藏
页码：102 / +
页数：11
相关论文
共 50 条
  • [41] Crystal structure of trans-(1,8-dibutyl-1,3,6,8,10,13-hexaazacyclotetradecane-kappa N-4(3),N-6,N-10,N-13)bis(5-methyltetrazolato-kappa N)nickel(II) from synchrotron data
    Kim, Dae-Woong
    Shin, Jong Won
    Kim, Jin Hong
    Moon, Dohyun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 173 - +
  • [42] Crystal structure, synthesis and thermal properties of tetrakis(4-benzoylpyridine-κN)bis(isothiocyanato-κN)iron(II)
    Wellm, Carsten
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 917 - +
  • [43] Crystal structure of poly[(2,2 '-bipyridine-kappa N-2,N')tetra-mu(2)-cyanido-kappa C-4:N;kappa N-4:C-manganese(II)disilver(I)]
    Theppitak, Chatphorn
    Chainok, Kittipong
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M179 - U86
  • [44] Crystal structure of poly[[(acetato-kappa O){mu(3)-N-[(pyridin-4-yl) methyl]pyrazine-2-carboxamidato-kappa N-4:N-1,N-2:N-4] copper(II)] dihydrate]: a metalorganic framework (MOF)
    Cati, Dilovan S.
    Stoeckli-Evans, Helen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 23 - +
  • [45] Crystal structure of tetrakis(mu-caproato-kappa O-2:O ') bis[(4-cyanopyridine-kappa N-1)copper(II)]
    Baruah, Sukanya
    Islam, Zinnatara
    Karmakar, Sanjib
    Das, Birinchi Kumar
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M195 - U128
  • [46] Crystal structure of trans-diaquabis(4-cyanobenzoato-jO) bis(N, N-diethylnicotinamide-kappa N)zinc(II)
    Akduran, Nurcan
    Necefoglu, Hacali
    Aydogdu, Omer
    Hokelek, Tuncer
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1374 - +
  • [47] Crystal structure of bis[(5-amino-1H-1,2,4-triazol-3-yl-kappa N-4)acetato-kappa O]diaquanickel(II) dihydrate
    Chernyshev, Victor M.
    Chernysheva, Anna V.
    Abagyan, Raisa S.
    Rybakov, Victor B.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 286 - +
  • [48] Crystal structure of bis{mu(2)-[(2-iminocyclopentylidene)methylidene]azanido-kappa N-2:N '}bis[(eta(5)-pentamethylcyclopentadienyl)zirconium(IV)] hexane monosolvate
    Becker, Lisanne
    Spannenberg, Anke
    Arndt, Perdita
    Rosenthal, Uwe
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M219 - U178
  • [49] Crystal structure of [tris(pyridin-2-ylmethyl)amine-kappa N-4]copper(II) bromide
    Bridgman, Emma C.
    Doherty, Megan M.
    Ellis, Kaleigh A.
    Homer, Elizabeth A.
    Lashbrook, Taylor N.
    Mraz, Margaret E.
    Pernesky, Gina C.
    Vreeke, Emma M.
    Oshin, Kayode D.
    Oliver, Allen G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 801 - +
  • [50] Crystal structure of bis(1,3-diaminopropane-kappa(2),N,N ')bis[2-(4-nitrophenyl)-acetato-kappa O]zinc(II)
    Roberts, T. J.
    Mehari, T. F.
    Assefa, Z.
    Hamby, T.
    Sykora, R. F.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M240 - U293
12345