Crystal structure of bis(benzylamine-kappa N)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-kappa N-4]iron(II) n-hexane monosolvate

被引：2
|
作者：
Dhifaoui, Selma [1 ]
Harhouri, Wafa [1 ]
Bujacz, Anna [2 ]
Nasri, Habib [1 ]
机构：
[1] Univ Monastir, Fac Sci Monastir, Lab Physicochim Mat, Ave Environm, Monastir 5019, Tunisia
[2] Lodz Univ Technol, Inst Tech Biochem, Xray Anal Lab, Stefanowskiego 4-10, PL-90924 Lodz, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
关键词：
crystal structure; hydrogen bonding; UV-vis spectra; iron(II)-porphyrin; benzylamine;
D O I：
10.1107/S2056989015024135
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Fe-II(C44H24Cl4N4)(C6H5CH2NH2)(2)]center dot C6H14 or [Fe-II(TPP-Cl)(BzNH(2))(2)]center dot n-hexane [where TPP-Cl and BzNH(2) are 5,10,15,20-tetrakis(4-chlorophenyl)porphyrinate and benzylamine ligands, respectively], the Fe-II cation lies on an inversion centre and is octahedrally coordinated by the four pyrrole N atoms of the porphyrin ligand in the equatorial plane and by two amine N atoms of the benzylamine ligand in the axial sites. The crystal structure also contains one inversion-symmetric n-hexane solvent molecule per complex molecule. The average Fe-N-pyrrole bond length [1.994 (3) angstrom] indicates a low-spin complex. The crystal packing is sustained by N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl hydrogen-bonding interactions and by C-H center dot center dot center dot pi intermolecular interactions, leading to a three-dimensional network structure.
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页码：102 / +
页数：11
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