A NOVEL HIGHLY DIASTEREOSELECTIVE SYNTHESIS OF CHIRAL DIHYDROTHIOPHENES FROM MESOIONIC COMPOUNDS

被引：24

作者：

AVALOS, M ^{[1
]}

BABIANO, R ^{[1
]}

CABANILLAS, A ^{[1
]}

CINTAS, P ^{[1
]}

DIANEZ, MJ ^{[1
]}

ESTRADA, MD ^{[1
]}

JIMENEZ, JL ^{[1
]}

LOPEZCASTRO, A ^{[1
]}

PALACIOS, JC ^{[1
]}

GARRIDO, SP ^{[1
]}

机构：

[1] UNIV SEVILLA,INST CIENCIAS MAT,DEPT FIS MAT CONDENSADA,E-41080 SEVILLE,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 21期

关键词：

D O I：

10.1039/C39950002213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thioisomunchnones undergo 1,3-dipolar cycloaddition with chiral nitroalkenes to afford stereoselectively 4,5-dihydrothiophenes by means of an unprecedented fragmentation of cycloadducts; the structures of these products have been established by single crystal X-ray structure analyses.

引用

页码：2213 / 2214

页数：2

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