COMPARISON OF DIFFERENT SYNTHESIS METHODS FOR NASICON CERAMICS

被引：36

作者：

GASMI, N ^{[1
]}

GHARBI, N ^{[1
]}

ZARROUK, H ^{[1
]}

BARBOUX, P ^{[1
]}

MORINEAU, R ^{[1
]}

LIVAGE, J ^{[1
]}

机构：

[1] UNIV PARIS 06,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 1995年 / 4卷 / 03期

关键词：

NASICON; SODIUM IONIC CONDUCTIVITY; COMPLEX IMPEDANCE SPECTROSCOPY; PHOSPHATES;

D O I：

10.1007/BF00488378

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Various methods for the synthesis of Na2Zr2P2SiO12 ceramics have been investigated. The methods differ by the order of mixing and the use of acetylacetone to decrease the reactivity of zirconium. The homogeneity of the powders prior to calcination has been checked by P-31 NMR. Their reactivity towards crystallization is not drastically different. The sintering behaviour is much better in powders in which the zirconium reactivity has been decreased. The effect of the processing on the resulting ionic conductivity of the ceramics has been studied.

引用

页码：231 / 237

页数：7

共 19 条

[1]

Goodenough J.B., Hong H.Y.-P., Kafalas J.A., Mat. Res. Bull., 11, (1976)

[2]

Von Alpen U., Bell M.F., Hofer H.H., Mat. Res. Bull., 14, (1979)

[3]

Boilot J.P., Salanie J.P., Desplanches G., Lepotier D., Mat. Res. Bull., 14, (1979)

[4]

Engell J., Mortensen J.S., Moeller L., Solid State Ionics, 9-10, (1983)

[5]

Kuriakose A.K., Ahmad A., Wheat T.A., Progress in Solid State Electrolytes, (1983)

[6]

Bayard M.L., Barma G.G., J. Electroanal. Chem., 91, (1978)

[7]

Yoldas B.E., Lloyd I.K., Mat. Res. Bull., 18, (1983)

[8]

Hosono H., Tsuschitani F., Imai K., Abe Y., Maeda M., J. Mater. Res., 9, (1994)

[9]

Boilot J.P., Colomban P., J. Mat Sci. Lett., 4, (1985)

[10]

Yde-Andersen S., Moeller L., Engell J., Lundsgaard J.S., Solid State Ionics, 9-10, (1983)

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