EFFECT OF A LIQUID-PHASE ON SUPERPLASTICITY OF 2-MOL-PERCENT-Y2O3-STABILIZED TETRAGONAL ZIRCONIA POLYCRYSTALS

被引:120
作者
HWANG, CMJ
CHEN, IW
机构
[1] Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan
关键词
creep; grain boundaries; liquid phase; plasticity; yttria‐stabilized tetragonal zirconia polycrystals;
D O I
10.1111/j.1151-2916.1990.tb09806.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A small addition of CuO to 2‐mol%‐Y2O3‐stabilized tetragonal zirconia polycrystals significantly enhances superplasticity by forming an amorhous grain‐boundary phase containing primarily Cu+, Y3+, Zr4+, and O2−. This phase apparently melts at around 1130°C, but it already provides a fast diffusion path even below the melting temperature. There are abrupt changes in stress exponent, activation energy, and grain size exponent across the melting temperature. Superplasticity is diffusion‐controlled below the melting temperature and is interfaced‐controlled above that. Copyright © 1990, Wiley Blackwell. All rights reserved
引用
收藏
页码:1626 / 1632
页数:7
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