Crystal structure of 2,6-dichloro-4-nitropyridine N-oxide

被引:0
作者
Prichard, Andrew M. [1 ]
Lynch, Will E. [1 ]
Padgett, Clifford W. [1 ]
机构
[1] Armstrong State Univ, 11935 Abercorn St, Savanah, GA 31419 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词
crystal structure; pyridine N-oxide; herringbone pattern;
D O I
10.1107/S2056989015017387
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C5H2C12N2O3, the nitro group is essentially coplanar with the aromatic ring, with a twist angle of 4.00 (6)degrees and a fold angle of 2.28 (17)degrees. The crystal structure exhibits a herringbone pattern with the zigzag running along the b axis. The herringbone layer-to-layer distance is 3.0075 (15) angstrom, with a shift of 5.150 (4) angstrom. Neighboring molecules are tilted at a 57.83 (4)degrees (ring-to-ring) angle with each other. The nitro group on one molecule points to the N-oxide group on the neighboring one, with an intermolecular O center dot center dot center dot N(nitro) distance of 3.1725 (13) angstrom.
引用
收藏
页码:O775 / U505
页数:5
相关论文
共 6 条
  • [1] OLEX2: a complete structure solution, refinement and analysis program
    Dolomanov, Oleg V.
    Bourhis, Luc J.
    Gildea, Richard J.
    Howard, Judith A. K.
    Puschmann, Horst
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 339 - 341
  • [2] Dual role of pyridine N-oxides in ruthenium porphyrin-catalyzed asymmetric epoxidation of olefins
    Gross, Z
    Ini, S
    [J]. INORGANIC CHEMISTRY, 1999, 38 (07) : 1446 - 1449
  • [3] Rigaku, 2011, CRYSTALCLEAR SM EXP
  • [4] Rigaku Corporation, 1998, REQAB
  • [5] SYNTHESIS OF VARIOUS CHLOROIMIDAZO[4,5-C]PYRIDINES AND RELATED DERIVATIVES
    ROUSSEAU, RJ
    ROBINS, RK
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1965, 2 (02) : 196 - &
  • [6] Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]