INTRAMOLECULAR CATALYSIS OF ESTER HYDROLYSIS BY METAL COMPLEXED HYDROXIDE ION - ACYL OXYGEN BOND SCISSION IN CO2+ AND NI2+ CARBOXYLIC-ACID COMPLEXES

被引:68
作者
WELLS, MA [1 ]
BRUICE, TC [1 ]
机构
[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106
关键词
D O I
10.1021/ja00458a020
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:5341 / 5356
页数:16
相关论文
共 43 条
[1]   INTRAMOLECULAR DISPLACEMENT OF ALKOXIDE IONS BY IONIZED CARBOXY-GROUP - HYDROLYSIS OF ALKYL HYDROGEN DIALKYLMALEATES [J].
ALDERSLE.MF ;
KIRBY, AJ ;
LANCASTE.PW .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1974, (12) :1504-1510
[2]   TRACER EXPERIMENTS ON ALKALINE HYDROLYSIS OF SOME OXALATE AMMONIA COBALT(3) COMPLEXES [J].
ANDRADE, C ;
TAUBE, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (07) :1328-&
[3]   MECHANISM OF METAL-ION-CATALYZED HYDROLYSIS OF ETHYL VALINATE- AND ETHYL LEUCINATE-N,N-DIACETIC ACIDS [J].
ANGELICI, RJ ;
LEACH, BE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) :2499-&
[4]   ACID IONIZATION CONSTANTS OF ALCOHOLS .1. TRIFLUOROETHANOL IN THE SOLVENTS H2O AND D2O [J].
BALLINGER, P ;
LONG, FA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (05) :1050-1053
[5]   STEREOPOPULATION CONTROL .5. FACILITATION OF INTRAMOLECULAR CONJUGATE ADDITION OF AN ALDEHYDE HYDRATE AND HEMIACETAL [J].
BORCHARD.RT ;
COHEN, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (25) :8313-8319
[6]   STEREOPOPULATION CONTROL .3. FACILITATION OF INTRAMOLECULAR CONJUGATE ADDITION OF CARBOXYL GROUP [J].
BORCHARD.RT ;
COHEN, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (26) :9175-9182
[7]   STEREOPOPULATION CONTROL .4. FACILITATION OF INTRAMOLECULAR CONJUGATE ADDITION OF HYDROXYL GROUP [J].
BORCHARD.RT ;
COHEN, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (25) :8308-8313
[8]   STEREOPOPULATION CONTROL .2. RATE ENHANCEMENT OF INTRAMOLECULAR NUCLEOPHILIC DISPLACEMENT [J].
BORCHARD.RT ;
COHEN, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (26) :9166-9174
[9]   STEREOPOPULATION CONTROL .5. CONFORMATIONAL SELECTION OF ALTERNATIVE OXIDATION PATHWAYS [J].
BORCHARDT, RT ;
COHEN, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (25) :8319-8326
[10]   MECHANISM OF CATALYSIS BY CARBOXYPEPTIDASE-A [J].
BRESLOW, R ;
WERNICK, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (01) :259-261