TRANSITION-METAL COMPLEXES OF TROGERS BASE AND THEIR CATALYTIC ACTIVITY FOR THE HYDROSILYLATION OF ALKYNES

被引：62

作者：

GOLDBERG, Y ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 03期

关键词：

D O I：

10.1016/0040-4039(94)02272-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium(III) and iridium(III) complexes of Troger's base (TB), of structural type TB(.)2MCl(3) (M = Rh, Ir), were prepared by treatment of TB with MCl(3). The rhodium complex readily catalyzed the hydrosilylation of alkynes with high regio- and stereoselectively observed in some cases.

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页码：369 / 372

页数：4

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