TRANSITION-METAL COMPLEXES OF TROGERS BASE AND THEIR CATALYTIC ACTIVITY FOR THE HYDROSILYLATION OF ALKYNES

被引：62
|
作者：
GOLDBERG, Y [1 ]
ALPER, H [1 ]
机构：
[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 03期
关键词：
D O I：
10.1016/0040-4039(94)02272-D
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rhodium(III) and iridium(III) complexes of Troger's base (TB), of structural type TB(.)2MCl(3) (M = Rh, Ir), were prepared by treatment of TB with MCl(3). The rhodium complex readily catalyzed the hydrosilylation of alkynes with high regio- and stereoselectively observed in some cases.
引用
收藏
页码：369 / 372
页数：4
相关论文
共 50 条
  • [1] REDUCTION OF ACYL LIGAND IN TRANSITION-METAL COMPLEXES BY CATALYTIC HYDROSILYLATION
    AKITA, M
    MITANI, O
    SAYAMA, M
    MOROOKA, Y
    ORGANOMETALLICS, 1991, 10 (05) : 1394 - 1399
  • [2] TRANSITION-METAL ISOCYANIDE COMPLEXES AND THEIR CATALYTIC ACTIVITY
    ADAMS, KP
    JOYCE, J
    NILE, TA
    REID, CD
    WALTERS, JM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 187 - INOR
  • [3] ENANTIOSELECTIVE CATALYSIS WITH TRANSITION-METAL COMPLEXES - HYDROGENATION AND HYDROSILYLATION
    BRUNNER, H
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 73 - ORGN
  • [4] HYDROSILYLATION OF OLEFINS WITH MONOSILANE CATALYZED BY TRANSITION-METAL COMPLEXES
    ITOH, M
    IWATA, K
    TAKEUCHI, R
    KOBAYASHI, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 420 (02) : C5 - C8
  • [5] Late transition-metal NHC complexes: Synthesis and catalytic activity
    Strassner, Thomas
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [6] CATALYTIC ACTIVITY OF GLASS-FIXATED TRANSITION-METAL COMPLEXES
    SCHWETLICK, K
    UNVERFERTH, K
    TIETZ, R
    PELZ, J
    JOURNAL FUR PRAKTISCHE CHEMIE, 1978, 320 (06): : 955 - 962
  • [7] THE CATALYTIC ACTIVITY OF TRANSITION-METAL COMPLEXES OF STERICALLY HINDERED ISOCYANIDES
    ADAMS, KP
    JOYCE, JA
    NILE, TA
    PATEL, AI
    REID, CD
    WALTERS, JM
    JOURNAL OF MOLECULAR CATALYSIS, 1985, 29 (02): : 201 - 208
  • [8] Catalytic activity of cyclobutadiene rhodium complexes in hydrosilylation and other transformations of alkynes
    Petrushina, Tatiana N.
    Nelyubina, Yulia V.
    Perekalin, Dmitry S.
    Shvydkiy, Nikita V.
    NEW JOURNAL OF CHEMISTRY, 2024, 48 (09) : 3952 - 3956
  • [9] THE CATALYTIC ACTIVITY OF TRANSITION-METAL COMPLEXES IN OXIDATION REACTIONS UTILIZING HYDROPEROXIDE
    WEERS, JJ
    THOMASSON, CE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 91 - FUEL
  • [10] STOICHIOMETRIC AND CATALYTIC FUNCTIONALIZATION REACTIONS OF ALKYNES AT TRANSITION-METAL COMPLEXES STABILIZED BY TRIPODAL POLYPHOSPHINE LIGANDS
    BIANCHINI, C
    PURE AND APPLIED CHEMISTRY, 1991, 63 (06) : 829 - 834
12345