TRANSITION-METAL COMPLEXES OF TROGERS BASE AND THEIR CATALYTIC ACTIVITY FOR THE HYDROSILYLATION OF ALKYNES

被引：62
作者：
GOLDBERG, Y [1 ]
ALPER, H [1 ]
机构：
[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 03期
关键词：
D O I：
10.1016/0040-4039(94)02272-D
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rhodium(III) and iridium(III) complexes of Troger's base (TB), of structural type TB(.)2MCl(3) (M = Rh, Ir), were prepared by treatment of TB with MCl(3). The rhodium complex readily catalyzed the hydrosilylation of alkynes with high regio- and stereoselectively observed in some cases.
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页码：369 / 372
页数：4
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