RECENT ADVANCES IN SYNTHETIC METHOD OF NITROGEN-HETEROCYCLES VIA AZA-WITTIG REACTION

被引:12
|
作者
EGUCHI, S
OKANO, T
机构
[1] Institute of Applied Organic Chemistry, Department of Applied Chemistry, Faculty of Engineering, Nagoya University
关键词
IMINOPHOSPHORANE; LAMBDA(5)-PHOSPHAZENE; AZIDE; PHOSPHOROUS(III) COMPOUNDS; STAUDINGER REACTION; AZA-WITTIG REACTION; TANDEM STAUDINGER REACTION AZA-WITTIG REACTION; TANDEM AZA-WITTIG REACTION ELECTROCYCLIC REACTION; PHOSPHAZIDE; NITROGEN HETEROCYCLES;
D O I
10.5059/yukigoseikyokaishi.51.203
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Recent advances in synthetic method of heterocyclic compounds by aza-Wittig reaction, i.e. , the imination using iminophosphoranes, are here reviewed. Examples are systematically presented depending on the direct cyclization route by intramolecular aza-Wittig reaction, or the sequential route via intermolecular aza-Wittig reaction, followed by various types of cyclizations such as electrocyclic reaction, Diels-Alder cycloaddition, and nucleophilic heterocyclization etc. The feasibility of this method in synthesis of nitrogen-heterocycles is emphasized in this review.
引用
收藏
页码:203 / 211
页数:9
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