(E)-3-Methyl-N'-(4-nitrobenzylidene)-benzohydrazide methanol monosolvate

被引:0
|
作者
Tang, Chun-Bao [1 ]
机构
[1] Jiaying Univ, Dept Chem, Meizhou 514015, Peoples R China
关键词
data-to-parameter ratio = 14.9; mean σ(C-C) = 0.004 Å; R factor = 0.058; single-crystal X-ray study; T = 298 K; wR factor = 0.142;
D O I
10.1107/S1600536812003868
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title hydrazone compound, C 15H 13N 3O3·CH 3OH, crystallized as a methanol solvate. The hydrazone molecule has an E configuration about the C=N bond and is almost planar, with a dihedral angle between the benzene rings of 5.3 (3)°. In the crystal, the hydrazone molecules are linked via the methanol solvent molecule through N - H⋯O and O - H⋯O hydrogen bonds, so forming chains propagating along the a-axis direction.
引用
收藏
页码:O602 / U1398
页数:7
相关论文
共 50 条
  • [41] (E)-4-Chloro-N′-(5-hydroxy-2-nitrobenzylidene)benzohydrazide
    Cao, Guo-Biao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2415 - +
  • [42] 2-Hydroxy-N′-(4-hydroxy-3-nitrobenzylidene)benzohydrazide
    Zhang, Zhen
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O301 - U2289
  • [43] Crystal structure of 4-[(E)-(4-nitrobenzylidene)amino]phenol
    Atioglu, Zeliha
    Akkurt, Mehmet
    Jarrahpour, Aliasghar
    Ebrahimi, Edris
    Buyukgungor, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O113 - U503
  • [44] 3-Chloro-N′-(3,5-dibromo-2-hydroxybenzylidene)benzohydrazide methanol monosolvate
    Li, Tian-Yi
    Qu, Yue-Gang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O330 - U304
  • [45] (E)-3-Bromo-N′-(4-methoxybenzylidene)benzohydrazide methanol solvate
    Cao, Guo-Biao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2086 - U1411
  • [46] N,N′-Bis(4-nitrobenzylidene)ethane-1,2-diamine
    Sun, YX
    You, ZL
    Zhu, HL
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : O1707 - O1708
  • [47] Crystal structure and Hirshfeld surface analysis of (E)-4-chloro-N-{242-(4-nitrobenzylidene)hydrazin-1-yl]-2-oxoethyllbenzenesulfonamide N,N-dimethylformamide monosolvate
    Purandara, H.
    Foro, S.
    Gowda, B. Thimme
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 394 - +
  • [48] Syntheses, Structures and Second-order Nonlinear Optical Behavior of (E)-N-(4-Nitrobenzylidene)-3,4-dimethylaniline and (E)-N-(3-Nitrobenzylidene)-3,4-dimethylaniline
    Unver, Hueseyin
    Karakas, Ash
    Durlu, Tahsin Nuri
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2010, 65 (02): : 185 - 190
  • [49] 4-[(1,3-Dioxo-2,3-dihydro-1H-benzo-[de]isoquinolin-2-yl)methyl]-N′-[(E)-4-nitrobenzylidene]benzenesulfono-hydrazide dimethyl sulfoxide monosolvate
    Bortoluzzi, Adailton J.
    Policarpi, Everton B.
    Mora, Cristiano
    Oliveira, Kely N.
    Nunes, Ricardo J.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O627 - U1795
  • [50] Heterocyclic Ions From N-Oxides of N-(4-Nitrobenzylidene)-2-cyclopropylaniline and N-(4-Nitrobenzylidene)-2-cyclopropylmethylniline: Formation, Isomerization, and Conversions
    E. V. Trofimova
    A. N. Fedotov
    R. A. Gazzaeva
    S. S. Mochalov
    Yu. S. Shabarov
    N. S. Zefirov
    Chemistry of Heterocyclic Compounds, 2003, 39 (2) : 205 - 212