WATER-SOLUBLE PHOTOINITIATORS - PRIMARY PROCESSES IN HYDROXY ALKYL PHENYL KETONES

被引：23
|
作者：
FOUASSIER, JP
BURR, D
WIEDER, F
机构：
[1] Laboratoire de Photochimie Générale, Unité de Recherche Associée au CNRS No. 431, Ecole Nationale Supérieure de Chimie, Mulhouse, 68093
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1991年 / 29卷 / 09期
关键词：
D O I：
10.1002/pola.1991.080290911
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Photopolymerization of acrylamide in water has been investigated in the presence of water-soluble hydroxy alkyl phenyl ketones. The processes involved in the excited states (alpha-cleavage, electron transfer, monomer quenching) have been studied by time-resolved laser-spectroscopy. Substitution at the para position of the phenyl ring changes drastically the reactivity and influences the possibility of synergistic effects when combining these photoinitiators with thioxanthone derivatives.
引用
收藏
页码：1319 / 1327
页数：9
相关论文
共 50 条
  • [21] Folded alkyl chains in water-soluble capsules and cavitands
    Gavette, Jesse V.
    Zhang, Kang-Da
    Ajami, Dariush
    Rebek, Julius, Jr.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 12 (34) : 6561 - 6563
  • [22] WATER-SOLUBLE DISULFONATED AROMATIC KETONES - PHOTOPHYSICAL AND PHOTOCHEMICAL PROPERTIES
    KRONFELD, KP
    TIMPE, HJ
    JOURNAL FUR PRAKTISCHE CHEMIE, 1988, 330 (04): : 571 - 584
  • [23] LIGHT-INDUCED POLYMER AND POLYMERIZATION REACTIONS .41. MIXTURES OF SULFONATED AROMATIC KETONES WITH ARYLIODONIUM SALTS NEW WATER-SOLUBLE PHOTOINITIATORS
    TIMPE, HJ
    KRONFELD, KP
    MAHLOW, R
    EUROPEAN POLYMER JOURNAL, 1991, 27 (01) : 69 - 75
  • [24] Alkyl Groups Fold to Fit within a Water-Soluble Cavitand
    Zhang, Kang-Da
    Ajami, Dariush
    Gavette, Jesse V.
    Rebek, Julius, Jr.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (14) : 5264 - 5266
  • [25] Binding orientation and reactivity of alkyl α,ω-dibromides in water-soluble cavitands
    Angamuthu, Venkatachalam
    Petroselli, Manuel
    Rahman, Faiz-Ur
    Yu, Yang
    Rebek, Julius, Jr.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 17 (21) : 5279 - 5282
  • [26] SYNTHESIS AND REACTIVITY OF WATER-SOLUBLE PLATINUM-ALKYL COMPLEXES
    HUTSON, AC
    SEN, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 69 - INOR
  • [27] Photoinitiators with functional groups. v. new water-soluble photoinitiators containing carbohydrate residues and copolymerizable derivatives thereof
    Liska, R
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (10) : 1504 - 1518
  • [28] Complexation of alkyl groups and ghrelin in a deep, water-soluble cavitand
    Zhang, Kang-Da
    Ajami, Dariush
    Gavette, Jesse V.
    Rebek, Julius, Jr.
    CHEMICAL COMMUNICATIONS, 2014, 50 (38) : 4895 - 4897
  • [29] Binding of alkyl halides in water-soluble cavitands with urea rims
    Yu, Yang
    Li, Yong-Sheng
    Rebek, Julius, Jr.
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (12) : 9945 - 9948
  • [30] Unusual orientation and reactivity of alkyl halides in water-soluble cavitands
    Hooley, Richard J.
    Gavette, Jesse V.
    Mettry, Magi
    Ajami, Dariush
    Rebek, Julius, Jr.
    CHEMICAL SCIENCE, 2014, 5 (11) : 4382 - 4387
12345