KINETICS AND THERMAL-DECOMPOSITION OF FE(III) AND UO2(II) COMPLEXES WITH EMBELIN (2,5-DIHYDROXY-3-UNDECYL-P-BENZOQUINONE)

被引：29

作者：

DHAR, ML

SINGH, O

机构：

[1] Department of Chemistry, University of Jammu, Jammu

来源：

JOURNAL OF THERMAL ANALYSIS | 1991年 / 37卷 / 02期

关键词：

Organometallics;

D O I：

10.1007/BF02055928

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermal decomposition of the complexes: [Fe(C17H24O4)1.5.2H2O]n and [UO2(C17H24O4.2H2O]n, and evaluation of kinetic parameters (E, Z and DELTA-S) by making use of Piloyan-Novikova, Coats-Redfern and Horowitz-Metzger equations are reported. The complexes are found to decompose in three well defined steps involving random nucleation mechanism. The intermediates formed during decomposition usually undergo further decomposition without remaining stable over a considerable range of temperature.

引用

页码：259 / 265

页数：7

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