BIMOLECULAR SOLID-STATE PHOTOREACTIONS IN THE ADDUCT CRYSTALS OF AN AROMATIC NITRO COMPOUND WITH AN AROMATIC AMINE

被引：9

作者：

ITO, Y ^{[1
]}

ASAOKA, S ^{[1
]}

SAITO, I ^{[1
]}

OHBA, S ^{[1
]}

机构：

[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 44期

关键词：

SOLID-STATE PHOTOCHEMISTRY; ADDUCT CRYSTAL; DONOR-ACCEPTOR COMPLEX;

D O I：

10.1016/0040-4039(94)88280-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Solid-state as well as solution-state photochemistry of the donor-acceptor complexes derived from an aromatic amine and an aromatic nitro compound was investigated. Of the twelve adduct crystals studied, only three involving m-DNB as the acceptor (9-MC/m-DNB, 9-EC/m-DNB and DMAP/m-DNB) were found to be photoreactive in the solid state, producing photoredox products probably through hydrogen abstraction by the excited nitro group. The FT-IR study has implicated that the NO2 group of m-DNB may be interacting with the donor's amino group in the crystalline state.

引用

页码：8193 / 8196

页数：4

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